Contributors

CSE - Customised Search Engine - Conversations on Innovations

Custom Search

Innovation network making progress

Corporate Crowdsourcing

Where my visitors live

InnoCentive: Challenges-All Categories

IdeaConnection :: Idea Contests

EUROPA - Research and Innovation - What's New

EUROPA - Research and Innovation: What's New in Innovation

Showing posts with label energy. Show all posts
Showing posts with label energy. Show all posts

Thursday, December 26, 2013

Waste to Energy: The Answer for Remote Islands is the title of my 2nd theme choice from Waste Management World (WMW) in order to introduce readers to the magazine



However, with appropriate levels of realism and pragmatism it is possible to adopt an approach that provides adequate protection to the local environment. Funding is often a major issue, and external support is an inevitable requirement if modern standards of environmental protection are to be met.

Due to their relatively small scale, the development and operation of on-island waste treatment and disposal facilities which meet increasingly stringent legislative requirements is a challenge.

While Islands can range in size from the smallest rock to the 2.1 million km2 of Greenland, for those with a human population, the issue of waste management can be problematic. Often isolated from end markets for recyclates, does waste to energy technology offer these remote communities the ideal solution?
by Andrew Street
SITA
SITA's waste to energy plant on the Isle of Man handles all of the island's waste and exports 5 MW to the grid - around 10% of the island's needs
Image credit: SITA
Due to their relatively small scale, the development and operation of on-island waste treatment and disposal facilities which meet increasingly stringent legislative requirements is a challenge. Whilst many remote island communities are not usually subject to the same level of legislative control as larger mainland states (for example, with regard to key EU Directives relating to waste management), it is usual for an island authority to seek to adopt an approach, and to introduce facilities and technologies that at least go some way to reflecting the high standards set out in European or other similar legislation. 
Within EU legislation, including that relating to waste management, such as the Waste Framework Directive and Landfill Directive, there is explicit recognition of the challenge of seeking to apply the same strict standards to small islands, and in these cases exemptions or derogations often apply.
This should not of course be seen as a 'licence' for any local, island based authority to adopt standards which give rise to wholesale environmental damage. Indeed given the reliance many small islands have on maintaining the environment either for the purposes of supporting tourism or local agriculture, that would clearly be counter-productive.


Lessons from history

In the past there have been plenty of examples of inappropriate waste management on small or remote islands, with very little attempt at adopting a sustainable approach that protects the local environment. On many small remote islands across Europe – and across the globe – indiscriminate dumping of waste was often the norm, with open burning and sometimes the tipping of the residue in a remote corner of the island. For example, for many years on the Greek island of Santorini waste was tipped over a high cliff. However this is no longer practiced and great strides have been made across many of the Greek islands in addressing these issues.
An extreme example of poor waste management – described in the worldwide press in 2012 as 'apocalyptic' and a 'floating toxic time bomb' – is the island of Thilafushi in the Maldives. With an indigenous population of around 330,000 but with nearly 800,000 tourist visitors each year, the Maldives archipelago is considered one of the most beautiful holiday destinations in the world. Of the 1200 islands in the group, 200 are inhabited and half of these are designated as resorts. Consequently, pressure on the environment is enormous, and waste management has simply not been adequately planned for or invested in.
The result is an open dump receiving over 300 tonnes of rotting waste each day, and on an island that is increasingly threatened by rising sea levels; this clearly means something has to be done.
The relatively small permanent population and the potential impact of a transient tourist population can place considerable pressure on local governments in terms of funding waste management services. Most remote island communities can only afford the most basic of waste management systems without external funding, simply because they do not have the local tax raising capacity to fund the full range of infrastructure required to deal with issues such as power generation and supply, water supply and wastewater treatment, let alone to manage solid waste in line with modern standards.

Population critical

There are examples of larger islands having the capacity to develop modern facilities, and to attract the investment required to do so. Two recent examples include the Isle of Man (population of 85,000) and Jersey (population of 98,000), both of which have state-of-the-art waste to energy facilities in place. A third example is the Western Isles (population of 26,000) off the north-western coast of Scotland, where a new integrated waste treatment facility has fairly recently been commissioned.
Western Isles Integrated Waste Management Facility
The Western Isles Integrated Waste Management Facility was the first in the UK to use anaerobic digestion to treat source separated organic waste to generate energy
Islands with much smaller populations simply could not support the development of this sort of facility without external funding from central government, or through grants. A current example of this is the Isles of Scilly – one of the most beautiful island archipelagos in Europe - but with a very small indigenous population of just 2200 people. Without the current commitment from the UK government to provide substantial funding it would simply not be possible for the island's local council to address the urgent need to replace an existing but ageing incinerator with a modern waste to energy facility and at the same time remediate a site which has been impacted by waste management over the last 50 years.
A parallel situation also arises for St Helena in the South Atlantic – one of the most remote islands in the world. St Helena, a British Overseas Territory, has an indigenous population of around 6600, and currently a relatively small number of tourists. That is due to change in the coming years with the development of a €240 million airport, which will make the island far more accessible. Major improvements to the Island's waste collection, treatment and disposal system are currently underway, but largely reliant on funding provided by the UK government.

Limited markets

The size of the local economy and industrial/agricultural base often cannot sustain consistently high levels of material reuse, limiting local markets for recycled materials and for compost products. This is particularly pertinent for an extremely remote location, where the transfer of materials off-island would be both expensive, and difficult to justify in terms of sustainability. This is clearly less of an issue for islands close to a mainland market, and in these cases recycling should be encouraged and established transport routes utilised to transfer materials to mainland markets for recycling.
There will however always be some scope for local reuse and recycling. Particularly in the developing world the imagination of the local population appears to have no limit when it comes to converting waste into something of real value. In most cases however, the market is limited by the size of the local economy, or impacted by the transient nature of any tourist traffic to the island. Therefore a degree of realism is needed when it comes to the level of recycling and reprocessing that can be sustained.
Additionally, on many islands there are seasonal increases in waste generation, and high levels of packaging associated with the necessary importation of food and other goods. These variations make it difficult to sustain both local and off-island commitment to resource efficient recycling and composting. Seasonal variations are often related to tourist activity, which although valuable to the local economy, will always bring additional pressures to the local environment, including the generation and importation of waste

Viable options

Experience indicates that there are normally just a few viable approaches to waste management that could be said to reflect 'good practice' (although not necessarily 'best practice') within a western, mainland state subject to strict legislative controls (such as would be the case for European Member States).
As outlined, it would not be appropriate to adopt the same approach to dealing with waste on a small remote island as one would for a large European metropolitan authority with access to local and central funding, a range of options for collection, treatment and disposal, and an established and mature market for a range of segregated materials and process outputs.
For a remote island community, or indeed any remote location, the range of realistic options for managing waste are inevitably much more limited. Experience across the globe shows that the most likely options to be adopted are:
St Helena
Existing landfill operation of St Helena in the South Atlantic – soon to be upgraded with funding from the UK government
Landfill: Reliance on landfill as the principal disposal route, with some limited recycling and reuse, but within the limits of local markets. Efforts are typically focused on ensuring that the landfill site (normally a single site, unless the island happens to cover a very large area, or is made up of an archipelago of islands) is developed and operated on a sanitary basis and is subject to appropriate levels of management and control so as to minimise the environmental impact. There are many islands across the world where this approach remains the strategy, and is the preferred approach going forward.
Hopkins Architects Ltd
Jersey's recently commissioned waste to energy plant will process up to 105,000 tonnes of waste per year and generate around 7% of the island's electricity Credit: Hopkins Architects Ltd
Thermal treatment: On some larger islands, where the quantity of waste is sufficient to justify the investment, it is quite common for the principal disposal route to be thermal processing through incineration. The preferred technology would be conventional incineration, and it would be unusual for a plant to be smaller than 10,000 – 15,000 tonnes/annum (although there are a few examples of smaller sized facilities on islands). Rarely is this on a combined heat and power (CHP) basis, simply because typically there will be few opportunities for use of the heat, but almost without exception power will be generated and exported to the local network. Any residual wastes that cannot be incinerated would be sent to landfill, along with incinerator residues.
What is notable is that it is very rare for other waste treatment technology to be introduced on small remote islands – whether that be the treatment of residual waste to create RDF for thermal processing (simply because it would not make sense to introduce two expensive treatment processes for such a small quantity of waste), or the treatment of organic waste by anaerobic digestion or composting.
Anaerobic digestion would normally be inappropriate in a remote island situation due to the relative complexity of the technology, and also the challenges of disposing of the digestate. There are often similar challenges in disposing of organic waste derived composts, simply because the local demand for such materials on remote islands is often minimal, and it could therefore end up being sent to landfill – which somewhat defeats the object of investing in a relatively expensive treatment process in the first place.

Conclusion

Developing and implementing a truly sustainable waste strategy for small islands can be challenging, and this becomes all the more difficult for those islands that are very remote. However, with appropriate levels of realism and pragmatism it is possible to adopt an approach that provides adequate protection to the local environment. Funding is often a major issue, and external support is an inevitable requirement if modern standards of environmental protection are to be met.
Andrew Street is a director at SLR Consulting Limited
Web: www.slrconsulting.com
More Waste Management World Articles
Waste Management World Issue Archives
Waste Management World Issue Archives

Thursday, June 24, 2010

New Green Construction Material Innovation_Low energy cement production by Celitement via IOM3: The Global Network for Materials, Minerals & Mining Professionals

"Low energy cement production
Researchers in Germany have developed a high-performance mineral binder, which, they say, can help reduce the energy consumption and CO2 emissions associated with cement production.
Celitement, the material’s trade name, is based on hydraulic calcium hydrosilicates."

Energy Saving

Celitement is made by forming calcium silicate hydrates in a hydrothermal reaction at temperatures between 150 and 200ºC. In a second step the autoclaved material is co-milled with a SiO2-rich material, such as quartz-sand.

‘Production of Ordinary Portland Cement (OPC) at temperatures of up to 1,450°C is a highly energy-consuming process,’ explains Dr Hanns-Günther Mayer, Managing Director of Celitement, a spin-out of the Karlsruhe Institute of Technology (KIT). ‘In addition, cement plants emit more than two billion tonnes of CO2 annually (2x10^9 tonnes CO2). In comparison to OPC Celitement has the potential to reduce both energy use and CO2 by up to 50%.’

Materials Strength:

 ‘During hydration, Celitement transforms to calcium silicate hydrate gel. This material is the cement hydrate, which defines the mechanical strength and stability of traditional concrete. Thus material properties of test samples made with Celitement, such as strength development and final compressive strength (up to 80 MPa) resemble those of samples made with OPC,’ adds Mayer.
Strength can be regulated by varying the mixing and processingparameters. ‘One big advantage of Celitement is the fact that it can be used just like any other cement.’
 Scale-Up
In spring 2011, a small pilot with a production rate of 100kg/day will start operation at KIT to perform extensive material tests and prepare scale-up.

REFERENCE:
Low energy cement production | IOM3: The Global Network for Materials, Minerals & Mining Professionals

  More on Celitement 

RELATED POSTS:

Materials and Environment-Embodied Energy of Materials

Nanoengineered concrete R & D to cut CO2 emissions (Feb 08, 2008)

WEDGE-A-WAR follows from Theory to Practice (Oct. 18, 2006)

 

Saturday, December 05, 2009

The truth about the cost of wind according to French Think-Tank. The answer may not be blowing in the wind?


To restore the truth about the cost of wind

By Vincent Le Biez translation . J.A.

Despite the counter arguments advanced by professionals of industrial wind turbines, the Institut Montaigne-in French- persists and signs: Wind turbine energy does not meet a need in France, considering the (current) structure of its power generation installations, composed primarily of nuclear and hydropower, which are recognised as being particularly sober (low) in terms of CO2 emissions. Moreover, the achievement of the Grenelle of the environment, ie 25 GW of wind power installed by 2020, would result in additional costs to society of about 2 to 3 billion euros. The current development of this technology is only due to the purchase price guaranteed to farmers by the state over 15 years, which are particularly attractive rates, funded by electricity consumers and which allow the creation of "green-rents" whose validity is questionable.

PS I more or less needlessly translated the above abstract to the full Pdf-Policy Paper "AEOLIAN POWER: CASTING MONEY TO THE WINDS? – July 2008 by Vincent Le Biez. from french to english. The full paper is still in french unless the abstract(s) stir sufficient interest for readers to request a full translation. Why put an s on abstract? Because I had translated before I spotted the english version giving access to at least to summaries and abstracts. The english abstract is a slightly fuller version and better written to my mind than the original french version.

NB. This work refers to the Energy production side - not to the the Energy Consumption side.

Whatever aspect one choses to look or from whatever angle there appears to be little room for complacency especially in "our developpeded world" cf graphs and physics from Prof. David MacKay, FRS., author of "Without Hot Air." freely available online.


REF. 2nd Abstract . The original english abstract on Institut Montainge's site


Ref. (In French)
1. the Institut Montaigne

2. the Institut Montaigne -Wind turbines with access to full Pdf. document and Video discussions discussions.

en référence à : Eoliennes & développement durable : rétablir la vérité sur le coût de l'éolien [INSTITUT MONTAIGNE] (afficher sur Google Sidewiki)


Related posts on Energy

The teraton challenge. A review of fixation and transformation of carbon dioxide, Danish work brought to us by RCS-The Royal Chemical Soc.,UK.

New comments-Conversations with B.J. Sovacool on Nuclear Power Plant, Coal Fired Power Generation, GHG emissions

CO2 Storage CCS and or CCU CO2 Use, Geological _Applied Earth Science Input,EU-China Geologists Co-operate to Find Onshore CO2 Sinks

What is significant Innovation, What to Innovate, Where to Innovate, How to Innovate_ Back to Basics

Information Overload Mastered_Renewable and Alternative Energy Sources Ranked_Review of solutions to global warming, air pollution, energy security

Alternative Energy CO2-GHG reduction_BEAT 2_A Biomass Environmental Assessment Tool free software for UK and UK-based companies

Tuesday, June 02, 2009

LINK to Light emitting diode-LED lighting up-date almost thwarted by Nature. Choose the right bulb.

Like many in this part of the world, I have a sample of all sorts of light sources including my recent change of 4 halogen spots 50W each for 4 LED spots (18 diodes each, power consumption per “spot”= 1W ) almost for the fun, I tell my sceptical or vested interest friends.

Link to full post.

Saturday, April 04, 2009

What is significant Innovation, What to Innovate, Where to Innovate, How to Innovate_ Back to Basics

In the spirit of "don't keep a good thing to ones-self", I introduced readers of my other management dedicated blog series "This-Above-All"_Energy Autonomy, Renewable Energies in France to two new books "My Energy Executive Choices 2008-2009". My early post was more of a parenthesis than a post truly dedicated book review. The reference to these two books gave me the chance to make a very short but well focused summary, However it in no way does justice to the importance and excellence of both books and their authors.

Refs:
My Energy Executive Choices 2008-2009

Two very good back-ground books to read and more so, to use.
1."Without Hot Air" by David J.C.MacKay free online or buy the print edition.
treats the basics of energy, demystifying confusion over units of measure and Energy Balance _ Production capacity (hard work and Jobs?) vs Consumption (Too easy for human and planetary good?)

2. C'est maintenant, 3 ans pour sauver le monde par Jean-Mark Jancovici et Alain Grandjean
[Now is the time - 3 years to save the world, by J-M Jancovici and A.Grandjean]
Energy and Economy policy for "Human Economy is essentially about how mankind transforms limited natural resources to make useful desirable products and services." quoted from the authors.

There are many points in common between the views of the authors of both books. Both aim to get to the essentials and these are entirely based on sound physical scientific principles. Not surprisingly, since the first author D. MacKay is a Professor in Physics at the famous Cavendish Laboratories Cambridge Univ and the 2nd book's joint authors, Jean-Marc Jancovici and Alain Grandjean are graduates of the France's foremost Engineering School, L'Ecole Polytechnique in Paris. J-M Jancovici is a leading energy and climate consultant and lecturer. Both UK's MacKay from UK and France's Jancovivi are Myth-Killers. Jancovici's website
"Manicore" much of which he translates to english, is a wealth of fairly simple "Myth Killing comparative calculations" to help fix one's ideas "orders of magnitude" and allow sensible, intelligent action. The similarities in MacKay and Jancovici's thinking and approaches are quite uncanny.("Great minds think alike"?) A. Grandejean whose work I am less familiar with, is an Economist and appears to be a no-nonsense, myth-killing economist.

Whereas David MacKay avoids as far as possible economics or cost-financial considerations, the two french authors not only take a strong stance on the physical aspects underlying the human (worth remembering) economy drawing from contemporary best selling author the erudite Professor Jared Diamond (recently cited in these blogs)[Link 1] [Link 2]. They also attempt to draw conclusions as to what energy-climate policies, politics ( and of course politicians) must inevitably address and master. They present their perception in a simple and clear manner that both politicians and the general public can understand. Both approaches whether explicitly (french authors) or implicitly (MacKay) consider the universal nature of energy as the fundamental unit, as all thermodynamics students (sciences and engineering) well know.

MacKay seeks to draw-up his energy accountancy (Production vs Consumption) in terms of KWs (KWh's and KWh's/day) whose usefulness in everyday life he explains in great length."

MacKay's catch quote is "Every BIG Helps" whereby he discards such mythology as "If we all do a little bit it will add-up to a lot":
"A lot of small improvements add up to an overall small improvement eg. 1.5% reduction in GHG/person gives an overall 1.5% improvement!
"A lot of "Bigs"" let's say 20% reduction in GHG emissions per person adds up to an overall big (20%) in a relatively short period to boot!
Such is the extent of gigantic effort required by leading scientists and experts such as UN's IPCC and most serious national scientific and engineering bodies world wide.

Jancovici and Grandjean are quote as follows:
"Human Economy is essentially about how mankind transforms limited natural resources to make useful desirable products and services." [Link]

Wednesday, November 26, 2008

New European Record-Science and Engineering - Solar PV-Photovoltaic Energy Converstion to Electricity Efficiency Reaches 39.4%

Record breaking news was announced by a team from Fraunhofer ISE-Institute for Solar Energy working within the EU project: Fullspectrum. Their work was brought to my attention today 26 Nov. 08 and described in some detail by the EU- Research Information Centre (RI).

Dr Andreas Bett, Department Head at Fraunhofer ISE, considers this to be one more decisive step in making it easier to generate a more cost-efficient use of these types of cells for terrestrial applications in a relatively short time and underlines the aim of such innovative projects:

"To achieve the highest conversion efficiencies and so help the young technology to become market competitive and to further sink (lower) the costs of generating electricity from the sun for the future."

The EU- RI centre's news letter article also pays some "self" tribute to the EU - FULLSPECTRUM -project which it remarks was chosen as one of the 40 success stories of the 6th Framework Programme.

More detailed information may be obtained from the following sources:

Sources:

1. The EU- Research information centre.
which also provides links to many other R & D themes eg. Energy

2. Original link
39.7% – New European Record Efficiency for Solar Cells achieved by Fraunhofer ISE

3. FULLSPECTRUM -project website

Saturday, April 12, 2008

Industrial Nanotech, EU-Official Building Code Approvals

Industrial Nanotech, Inc. Energy Saving Coating Receives Official Building Code Approvals For the European Union.

Industrial Nanotech, Inc. (Pink Sheets:INTK), a contender in the emerging global leadership nanotechnology mouvement, announced today that the Company's patented Nansulate energy saving protective coatings are now approved under the stringent EU building codes. The approval certification for building construction standards in the European Union was obtained by the Company's distributor for Italy and Spain, Aktarus Group, based in Milan, Italy.

Industrial Nanotech Inc., it is claimed, is quickly emerging as a global nanoscience solutions and research leader. The Company develops and commercializes new and innovative applications for nanotechnology. Additional information about the Company and its products can be found at their websites ([Industrian Nanotech[Link] and Nansulate [link]).

Stop press: Adapted from (PRWEB)April 12, 2008, Naples, FL

Wednesday, April 09, 2008

No_Holds_Bard: An Innovative Energy Network Brings Carbon-Credit Hope-Highlighted by my poem "THE DC NETWORK" High Voltage Direct Current -Also Sound Advice on HIV#links#links

No_Holds_Bard: An Innovative Energy Network Brings Carbon-Credit Hope-Highlighted by my poem "THE DC NETWORK" High Voltage Direct Current -Also Sound Advice on HIV#links#links

Sunday, April 06, 2008

Sustaining Future: Carbon Negative Energy Source

Sustaining Future: Carbon Negative Energy Source

Thursday, February 21, 2008

Engineering Job call - Skill needs in energy industry - Significant decline in science, engineering and technical recruits

ref: ‘Skills needs in the energy industry’ report by the Energy Institute

"Energy skills shortage: a boardroom issue"

Future skills shortages and leadership development needs in the energy sector should be treated as strategic boardroom issues, according to the Energy Institute (EI).

This was one of the key recommendations drawn from surveys conducted by the EI in partnership with Deloitte , the management consultancy, and Norman Broadbent,an organisation dedicated to the search for executive talent in the energy sector, between 2005 and 2007.

A summary of the ‘Skills needs in the energy industry’ report was presented at International Petroleum Week, an annual four-day programme of major conferences and functions hosted in London by the EI.

According to EI, a significant decline in recruits, especially those with science, engineering and technical skills is reported.


For the first time, IP Week featured a seminar specifically dedicated to the issue of skills needs in the energy industry, during which delegates from 12 different oil and gas producing countries heard experts outline additional solutions.

The media report may be found at Energy Institute (EI)[link_pdf].

Other online resources from the Energy Institute are:


EI Publications online
Standard Test Methods
Modern Petroleum Technology
WPC Proceedings
Transport Fuels Technology Update Service
Hearts and Minds Toolkit
Safe staffing arrangements
Offshore technical guidance catalogue
Fuel and Energy Abstracts
Croner’s Energy Management
EI Yearbook



Source [link].

Friday, February 08, 2008

Nanoengineered concrete R & D to cut CO2 emissions

Nanoengineered concrete could cut CO2 emissions?

In a previous note on commercial or near commercial innovation, I recorded work on cement manufacturing at lower temperatures, thus saving energy and reducing CO2 emissions.

The MIT report (below_near the end of my entry) appeared to provide an opportunity to record both one high profile longer termed R&D work in Nanoengineering and the more mundane close to production, often overlooked by the main dailey press media.

Having recently received an invitation, among many others, to attend a 2 day conference, Global Fuels Conf. & Awards, held in London on 4-5 Feb. 08, [Link-html] reporting on Industrial progress and R&D work, many of which involved CO2 reduction in cement manufacturing, including it's use in steelmaking slags.

[Link-html]

The following entry "Nanoengineered concrete could cut CO2 emissions? " which was my initial motivation to weblog, appears to belong to the longer termed (LT) research category unless the financial backing from the french company Lafarge pushes forward the project and in doing so achieve quicker and improved ROI-Return on Investment.


Nanoengineered concrete could cut CO2 emissions?
CAMBRIDGE, Mass.--While government leaders argue about the practicality of reducing world emissions of carbon dioxide, scientists and engineers are seeking ways to make it happen.
One group of engineers at MIT decided to focus its work on the nanostructure of concrete, the world's most widely used material. The production of cement, the primary component of concrete, accounts for 5 to 10 percent of the world's total carbon dioxide emissions; the process is an important contributor to global warming.


In the January issue of the Journal of the Mechanics and Physics of Solids, the team reports that the source of concrete's strength and durability lies in the organization of its nanoparticles. The discovery could one day lead to a major reduction in carbon dioxide emissions during manufacturing.


Could be worth repeating that the above reported MIT research was funded in part by the Lafarge Group according to
Eurekalert[Link]

In guise of a conclusion:
WHAT IS PRETTY CERTAIN IS THAT MANY MORE E-MISSIONS WILL CUT CO2 EMISSIONS WITHOUT CUTTING JOBS!

May I take this opportunity to remind my readers that I travel for work missions only according to standard working request procedures, transportation mode being, of course, at the initiative of the requesting firm, however where distance is involved and when possible, rail travel is preferred. The latter is a considerable sacrifice, as I love flying!

Acknowledgements:
1. With thanks to Danish Nano & Nilt News letter who drew my attention to this MIT
work.
2. Global Fuels Awards
Four categories are open for nominations:

1 Outstanding alternative fuel project (cement or lime company)
2 Most innovative technology for alternative fuel use

3 Outstanding electrical energy efficiency project award (cement or lime company)

4 Most innovative technology for electrical energy efficiency

Tuesday, June 12, 2007

The Metallurgy of CO2 absorption with resulting Hydrogen gas production _Wedge a War

The first post on this theme was entitled "Wedge-A-War: Any Old Iron?, Corrosion & Natures Processes, the latter "Nature's Processes" being the title of a book of poems by John Updike. It draws attention to the role of corrosion of iron in a wet (humid-H20) carbon dioxide (CO2) environment resulting in the production of iron carbonate and hydrogen gas as the products of the reaction. This is repeated in the chemical form below together with a little poem written for the occasion. Full references were given in the previous entry "Wedge-a-War. Any Old Iron?"




Fe(s)+ H2O(l) +CO2(g)=> FeCO3(s) +H2(g)
iron +water+carbon dioxide => iron carbonate + H2
(where s=solid, l=liquid, g=gas.)

Let the Heavenly Steel Chorus hear -
Metallurgists, Steelmakers, Geologists, dear
Chemical Engineers and Ecologist's plea.
From humble steelmaking, sometime war-mongering,
To white knight planet saviour - eco-engineering,
For "Now's the time and now's the hour" for CO2 sinking,
For scientific method and controlled tinkering.
The above corrosive reaction begs the question:
Any old iron?

ref: to initial back-ground from "Corrosion Mechanisms & Control in Hydrocatbon Exploration and Production Operations", by Dr. Dan Kirkwood in the now, out of print; "Journal of the Metallurgical Club -Strathclyde University" 1992-93, p43-58.

In fact it is well known that several other metals behave in a similar fashion in these matters. A fairly recent reference to such metals and reactions has been echoed by Kurzweil [Link] reported initially and at more length in CNet news [Link].

Both tech watchers, Kurzweil and CNet report two approaches:

I. Involves Aluminium catalysed,dis-inhibited by Gallium,The method is outlined, costs estimates given, patents filed and a company, "AlGalCo", created to exploit the inventions and innovations.

"Purdue University professor Jerry Woodall has discovered a way to make hydrogen out of a reaction of water and an alloy of aluminium and gallium. Woodall estimates that the technique could produce fuel that would compete with gas at $3 a gallon (assuming current prices for aluminium, which are above $1 a pound). Woodall considers that the higher actual fuel cost could be off-set by the higher efficiencies of hydrogen engines.

The Purdue Research Foundation holds title to the primary patent, which has been filed with the U.S. Patent and Trademark Office and is pending. An Indiana start-up company, AlGalCo, is licensing the patent and will try to commercialize the idea."

II. Involves Magnesium. The company Ecotality associated with the Jet Propulsion Lab (USA) managed by CalTech [Link] to exploit the the so called Hydratus principle[Link]. More on the uses of magnesium may be found at Magnesium.com's[Link]

III. Involves extracting hydrogen from a reaction between sodium, water and silicon. The company exploiting this avenue is New York's Signa Chemistry [Link]

IV. Last but not least is the EU and Israel's Weizmann Institute, Zn powder produced H2, Solzinc process[Link] Unlike the previous examples whereby hydrogen is obtained from corrosion like processes the Solzinc project is a classical reduction of zinc oxide by carbonaceous material at elevated temperatures (>1000°C)readily depicted by the Richardson-Ellingham Diagramme. High temperatures are obtained by using mirror concentrated solar power installation at the Weizmann Institute in Israel.



If this is not sufficient, the biologists too, seem keen to "Wedge some Wars" from their angle, if only to keep the metallurgists on their toes. CNet news reports again
"Stanford University professor James Swartz, who by contrast,has found a micro-organism that takes sunlight and splits water molecules. Swartz's work has generated a start-up called Fundamental Applied Biology."

I would not like to end on a note highlighting our biologist colleagues no matter how highly distinguished.

Let me point out that there is a very interesting list of metals and their carbonates all of which by definition are capable of absorbing CO2, and most likely producing Hydrogen subject to determining the correct thermodynamic, kinetic conditions. Choices will subject to the economic, "social and environmental" climate in which they are required to operate.

The efficiency of the hydrogen energy vector for combustion has been dealt with in depth in a very well reference section of the free Encyclopaedia "Wikipedia" [Link].

Wednesday, October 18, 2006

WEDGE-A-WAR follows from Theory to Practice


I wish simply to draw the chance visitor's attention to my additions "Socolow Wedge Best Practice" in my field of Metallurgy, Materials & Processing cf. also Links Section. The processes (1st one) invented by Fray-Farthing-Chen (FFC) known as the Cambridge Process [UK] following its University Start-Up Co., has produced two full companies, * BTi-British Titanium and, for a full range of metals and alloys, Metalysis and, (2nd one) Geopolymer Institute, Davidovit's cement, work at 1/3 to 1/2 the temperatures used by more classical routes (promising energy economies). Lets add to the previous two initiatives: process-product-market, approaches, a stricly process oriented "inventions & innovations" that of the recently created Thermokin ,by the inventor, J. Haiun. Thanks to it's; "blade-less turbine"-thermokinetic-compressor which controls, heat and speed, using and canalising the propeties of gases during reversible -forced transitions; subsonique to supersonic and back. Thermokinetics is the name coined for this field. Thermokin announces considerable potential energy saving of about 10% at low investment and maintenance costs.

I found these developments to be encouraging therefore I shall be pleased to help readers (at least among the less specialised) formulate any comments or questions to the people directly involved.

*PS. since 1st post, I have learned, cf.link BTi, that a conflict has arisen between BTi and Metalysis together with major Tech. backer QinetiQ.

.Je souhaite, simplement, tirer à l'attention des visiteurs mes additions: "Cales de Socolow - Meilleures Pratiques" dans mes domaines de spécialisations Métallurgie, Matériaux, Procédés cf. Links Section. Les procédés (1) inventé par
Fray-Farthing-Chen (FFC) nommé le FFC Cambridge Procédé [UK] (électrolyse avec sels fondus comme électrolytes ) et après ses débuts comme un "start-up" universitaire, à conduit à la création de deux sociétés; BTi-British Titanium et, pour une large gamme de métaux et d’alliages, Metalysis puis (le 2ème) , Geopolymère: par l'ingénieur chimiste distingué Davidovit's - ciments, béton ; travaillent à températures 1/3 à 1/2 des températures de fabrication classiques. Ajoutons aux inventeurs-innovateurs précédents et leurs sociétés: "procédés – produit - marché", la société Thermokin, récemment crée par J.Haiun, dans le domaine des procédés. Grâce à sa "turbine (sans pales) - compresseur thermocinétique" exploitant et canalisant les proprietés des gazes lors des transitions "réversible forcée" ; subsonique=>supersonique=> subsonique (nommé thermocinétique). Thermokin annonce des économies d’énergie potentielles, importantes de l'ordre de 10% pour un investissements en équipement et maintenance relativement modeste.

Ces développements méritent encouragement. Je serai heureux de vous aider (les moins spécialisés entre vous, tout au moins) à formuler commentaires, suggestions ou questions à destination des intéressés.

Enjoy your visit.
Lire avec plaisir.